新疆图拉尔根镁铁-超镁铁质杂岩体镍铜钴成矿岩浆作用过程:流体化学与碳同位素组成制约     

张铭杰  班舒悦  李思奥  宋哲  仇哲  李立武  惠卫东  李中平 《岩石学报》2020,36(12):3673-3682

东天山造山带的图拉尔根镁铁-超镁铁杂岩体为一个早古生代长期活动的幔源岩浆通道，大型铜镍钴硫化物矿体赋存于Ⅰ号超镁铁质岩体的顶部，不同类型岩石中辉石矿物的流体挥发份化学组成以H₂O为主（平均91%，5400.4mm³/g），其次为H₂（2.0%）、H₂S（2.3%）和CO₂（2.1%）；赋矿角闪橄榄岩中CO₂和H₂S含量最高，辉长岩中流体挥发份含量低于辉石橄榄岩和橄榄辉石岩等岩浆早期结晶的岩石。CO₂和CH₄的δ¹³C值位于地壳与甲烷氧化的范围内，甲烷同系物的碳同位素组成具有正序分布模式，部分样品（TLG512）释出的CH₄和C₂H₆具有较重的δ¹³C值和反序分布特征。表明I号岩体不同类型岩石可能是不同期次岩浆活动的产物，成矿岩浆具有富H₂O和H₂S的特征，可能起源于被流体交代的亏损地幔源区，混染壳源组分可能为俯冲板片来源蚀变沉积有机质组分。  相似文献   

西藏班戈地区后碰撞花岗岩岩石成因及其对班公湖--怒江缝合带演化的约束     

鲁洪涛  黄维平  刘振宇  郑明  李海峰 《吉林地质》2020,39(1):12-23

本文对班戈雪如岩体似斑状二长花岗岩进行了LA-ICP-MS锆石U-Pb定年、微量元素和全岩地球化学研究,探讨了其形成年代、成岩条件和构造背景。结果表明雪如岩体侵位于晚白垩世晚期(76±1 Ma),锆石饱和温度计和锆石Ti温度计计算其成岩温度分别为760~810℃和738~814℃,较低的锆石相对氧逸度反映成岩环境为还原环境。全岩地球化学分析结果显示其具有高硅、富碱和准铝质--弱过铝质特征,大离子亲石元素和LREE富集,高场强元素和HREE相对亏损。雪如岩体是中地壳部分熔融的产物,源区残留相为斜长角闪岩相,岩浆结晶过程中发生角闪石和斜长石的分离作用。地球化学投图结合区域构造演化显示其形成于后碰撞伸展环境,表明班公湖-怒江缝合带中段地区在晚白垩世晚期已经进入后碰撞伸展阶段。  相似文献   

海南抱伦金矿区辉绿岩脉的成因及其对金成矿的启示     

周岳强  许德如  赵朝霞  单强  董国军  宁钧陶  朱昱桦 《岩石学报》2020,36(2):541-559

海南抱伦金矿区的金矿脉与大量辉绿岩脉在空间上紧密相关。在详细的野外地质调查基础上,本文对这些辉绿岩脉开展了岩相学和矿相学观察、全岩主量和微量元素分析、Sm-Nd同位素组成分析、金丰度分析以及SHRIMP锆石U-Pb定年,初步探讨了辉绿岩脉的成因、岩浆演化和构造背景以及与金成矿作用的关系。地球化学分析结果表明,辉绿岩脉形成于拉斑玄武质岩浆,主要为左倾型的稀土配分模式;相对N-MORB,富集Sr、K、Rb和Ba等LILE和Th,亏损HFSE,ε_(Nd)(t)为0. 3～5. 6,说明岩浆源区为受到俯冲带含水流体影响和少量地壳混染的亏损地幔。辉绿岩脉的SHRIMP锆石U-Pb年龄为231. 6±2. 6Ma,与尖峰岭花岗质岩体的年龄(236±3. 5Ma～249±5Ma)相近,产出位置相邻,类似于海南兴隆地区的双峰式侵入岩,表明它们产出于造山后伸展环境。辉绿岩脉对应的岩浆富含CO_2、H_2O、F、K、Rb、Ba和适量的S,为抱伦金矿等单金矿床中Au的合适载体。金丰度分析结果表明,辉绿岩脉中的Au曾被活化迁移。再结合辉绿岩脉成岩年龄与抱伦矿区的成矿年龄在误差范围内一致的特征,认为抱伦金矿的Au可能来源于辉绿岩脉。  相似文献   

鄂尔多斯盆地南部奥陶系马六段白云岩特征及形成机制研究     

刘丽红  王春连  李丽霞  杜治利  唐跃  韩淼 《中国地质》2020,47(3):810-820

鄂尔多斯盆地马六段在盆地大部分地区被剥蚀,仅在盆地周缘地区分布,因此,有关该盆地马六段白云岩成因研究较少。本文通过对马六段白云岩岩石学特征、阴极发光特征、微量元素特征以及碳氧同位素地球化学特征进行分析,对鄂尔多斯盆地南部马六段白云岩特征及形成机制进行了研究。研究结果表明,盆地南部马六段白云岩主要由细—中晶白云岩组成,白云石具"雾心亮边"结构,阴极发光呈暗红色光。微量元素总体上具有较低的Fe、Mn值,平均值分别为447×10~(-6)和62×10~(-6),较高的K、Na值,平均值分别为517×10-6和252×10~(-6),以及中等含量的Sr元素值,平均值为155×10~(-6)。δ~(13)C值平均为-0.617‰,δ~(18)O值平均为-7.6‰,以上特征均反映出海源流体特征。白云石的"雾心"和"亮边"结构中微量元素含量相差不大,认为是在相同成岩环境的不同成岩阶段形成,其中"雾心"形成于浅埋藏环境的渗透回流白云石化作用,而"亮边"是在深埋藏环境下对早期白云石的调整和加强。  相似文献   

Nature and Evolution of Pre-Neoproterozoic Continental Crust in South China: A Review and Tectonic Implications     

WANG Kai  DONG Shuwen  YAO Weihu  ZHAO Tianyu 《《地质学报》英文版》2020,94(6):1731-1756

South China as an amalgamation of the Yangtze and Cathaysia blocks is composed of Archean to Mesoproterozoic basement overlain by Neoproterozoic and younger cover. Both the constituent Yangtze and Cathaysia blocks contain well-preserved Neoproterozoic rocks that have been extensively studied in terms of the age and tectonic nature, but less is known about their earlier crustal history due to the incomplete rock record. Recent efforts in investigating the yet survived crustal nature based on isotopic and elemental signatures preserved in igneous and sedimentary rocks have steadily improved our knowledge about the pre-Neoproterozoic continental crustal evolution in South China. In this paper, we summarize the up-to-date pre-Neoproterozoic records, including petrological, geochronological, geochemical and geophysical data, across South China, and discuss its spatiotemporal patterns of the pre-Neoproterozoic crust and the relevant tectonic events. While the xenocrystic/inherited and detrital zircon records suggest widespread Archean (mainly ca. 2.5 Ga) crustal components within both the Yangtze and Cathaysia blocks, exposed Archean rocks are only limited to isolated crustal provinces in the Yangtze Block. These Archean rocks are dominated by TTGs (tonalite-trondhjemite-granodiorite) with varied ages (3.3–2.5 Ga) and zircon Hf isotopes, indicating a compositionally heterogeneous nature of the Archean Yangtze Block and, by inference, the development of multiple ancient terranes. The early Paleoproterozoic (2.4–2.2 Ga) tectonomagmatic events characterize the western Yangtze Block and are supportive of an east-west subdivision of the Yangtze basement, whereas the late Paleoproterozoic (2.1–1.7 Ga) orogeneses may have affected a larger area covering both the western and eastern parts of the Yangtze Block, and also the Cathaysia Block. The eastern Yangtze Block with generally northeastward-younging late Paleoproterozoic magmatism and metamorphism likely experienced a prolonged 2.05–1.75 Ga orogenic process welding the various Archean proto-continents, consistent with the documentation of a buried late Paleoproterozoic orogenic belt imaged by deep seismic profiling from its central part and of a slightly older ophiolitic mélange in the northern part. The Cathaysia Block was probably involved in a short-lived 1.9–1.8 Ga orogenic event. The two orogeneses overlapped in time and may have contributed to the cratonization of a possible unified South China, and are referred to be linked with the assembly of the Nuna Supercontinent. The subsequent late Paleoproterozoic to early Mesoproterozoic rift successions and intrusions (1.7–1.5 Ga) in the southwestern Yangtze Block, and the ca. 1.43 Ga rifting in Hainan Island of the Cathaysia Block could be responses to the Nuna break-up. Late Mesoproterozoic (1.2–1.0 Ga) magmatism of varied age and nature in different localities of the Yangtze Block is reflective of a complex tectonic process in the context of the assembly of the Rodinia Supercontinent. Similar-aged metamorphism (1.3–1.0 Ga) is recorded in Hainan Island, reflecting the Grenvillian continental collision during the Rodinia assembly, but further studies are necessary to better constrain the late Mesoproterozoic tectonic framework of South China.  相似文献   

胶东焦家断裂带蚀变岩非镜像对称特征及其地质意义     

张亮亮  马生明  朱立新  林少一  周明岭  徐忠华  王建 《大地构造与成矿学》2020,(2):276-288

焦家断裂蚀变带是胶东地区最重要的控矿构造之一。该断裂带控制的矿床是创立“焦家式”金矿理论的重要实例基础。目前,焦家断裂带累计探明Au资源储量超过1200 t,并且还在不断增加,展现了深部重要的勘查和研究价值。焦家断裂带控制的矿体主要赋存在主断面下盘,断裂带发育于花岗岩中时,上盘发育钾长石化花岗岩、绢英岩化花岗岩、黄铁绢英岩化花岗质碎裂岩、(黄铁)绢英岩质碎裂岩,下盘发育黄铁绢英岩质碎裂岩、黄铁绢英岩化花岗质碎裂岩、黄铁绢英岩化花岗岩和钾化花岗岩,蚀变类型在主断面两侧呈现对称分布特征。但是在岩性特征、结构构造、蚀变强度、化学成分等方面差异明显,表现出非镜像对称特征。上盘蚀变岩厚度大于下盘,下盘花岗岩的构造破碎程度比上盘花岗岩更严重;断裂带上盘黄铁矿含量低、一般无矿化显示,下盘黄铁矿含量高,出现金矿化;断裂带上盘的中生代花岗岩中韧性变形不发育,以脆性破裂为主,下盘发育明显的韧性变形;断裂带上下盘不同蚀变带的成矿元素Au,矿化剂元素S,成矿伴生元素Ag、Pb、Zn,亲石分散元素Ba、Sr以及主量元素Na2O、MgO含量具有差异性,指示焦家断裂带主断裂面两盘经历了不同的成矿作用过程,下盘花岗岩的热液蚀变作用与成矿作用的关系更为密切。依据焦家断裂带不同蚀变带元素的非镜像对称性特征,可利用上、下盘花岗岩和构造蚀变带的地球化学标志识别矿体或者不同蚀变带的位置,对认识“焦家式”金矿床的成因机制、预测深部成矿前景、指导深部找矿具有重要理论和实际意义。  相似文献   

LA-ICPMS Zircon U-Pb Age of the Zhongchaye Vermiculite Deposit in Laiwu, Shandong Province     

LI Jie  LI Shiyong  SU Xuliang  SONG Mingchun 《《地质学报》英文版》2020,94(5):1721-1723

  相似文献   

西藏甲玛铜多金属矿床磁黄铁矿标型矿物学特征及其地质意义   总被引：2，自引：0，他引：2  

杨阳  唐菊兴  吴纯能  林彬  唐攀  张泽斌  何亮  祁婧  李怡萱 《矿床地质》2020,39(2):337-350

甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%～60.71%,平均为60.38%,w(S)为38.18%～38.69%,平均38.35%,化学分子式为Fe_8S_9～Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%～59.57%,平均为59.10%,w(S)为39.28%～39.95%,平均39.59%,化学分子式为Fe_5S_6～Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   

安徽庐枞盆地泥河玢岩型铁矿床地质-原生晕地球化学找矿模型   总被引：1，自引：1，他引：0  

张赞赞  张舒  吴明安  写熹  吕博  魏国辉 《矿床地质》2020,39(2):305-325

开展长江中下游地区玢岩型铁矿床轴向原生晕地球化学分析及建模,可弥补地球物理勘探结果的多解性及探测精度的局限性,对定位和评价深部盲矿体具有至关重要的作用。文章在以往研究的基础上,开展庐枞盆地泥河玢岩型铁矿床钻孔原生晕的研究工作,采用多元统计分析方法,查明了主要成矿指示元素在不同地质体中的富集和亏损,确定了磁铁矿、硫铁矿和硬石膏矿体的矿中、近矿及远矿指示元素组合,结合矿床成因模型,建立了泥河玢岩型铁矿床地质-原生晕地球化学找矿模型,通过罗河和小包庄玢岩型铁矿床的佐证,认为该模型可以应用于长江中下游成矿带玢岩型铁矿床的勘探工作中。  相似文献